Hi and thank you for your question! While in theory it is possible to do adjustments to the shape and form of smile, it is quite difficult to achieve desirable results and even if it works well one time, since Botox effects are temporary, it will go away soon and you need to redo it, and risk unexpected results again. Some degrees of asymmetry is natural and is present in everyone and based on the picture, your smile does not seem to be noticeably asymmetry (although I understand that it is how you feel about it that matters). Given all, I do not recommend doing Botox for this indication. I hope it helps and good luck!
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